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Toxic Site Reclamation
Since the toxic constituents of industrial effluents are known in most cases, their treatment is easy. However, the waste disposal sites their chemistry is often complex. Although incineration (drying and then burning to ashes in a furnace) or chemical treatments are suggested for treatment of these sites, biotechnological approaches involving biodegradation is considered more attractive. Companies like BioTechnica are working on treating polluted sites in situ.

In this connection, it is interesting to note that the first patent ever awarded for a living organism was given to Dr. Ananda Chakrabarty (USA) for developing a microbe designed to biodegrade spilled oil.

There has been a dabate on whether or not to release genetically engineered microbes for treatment of toxic sites. It is argued that biotechnology products (genetically engineered microbes) parallel toxic chemicals in many respects and unlike chemicals, they have the capacity to reproduce and spread beyond the initial release sites. They may even transfer novel genes into other naturally occurring organisms, thus causing the risk of developing what are described superbugs.

In view of the above, ‘Occidental Chemical Corporation’ company of USA is conducting their work on effluents from toxic waste sites (Love Canal and other polluted sites in USA), in closed reactors, one such experiment was conducted at Hyde Park landfill site at the northwest corner of Niagara, New York.

This site occupies just over 6 hectares of land and contains an estimated 73,000 tonnes of chemical waste. The site was used from 1953 to 1975 to dispose off, a wide range of waste materials including chlorinated organics. For treatment of this site, a clay cover was placed on the landfill in 1978, and a leachate-collection system was installed around the perimeter in 1979. From this system 230 m3 of leachate per week was shipped to a nearby treatment involved carbon absorption, thus making the effluent suitable for discharge. This solution was not found suitable on a long term basis.

Therefore, the Hyde Park waste water was subjected to biotreatment in sequencing batch reactors (SBRs), where biodegradation rate of some more persistent chemicals was accelerated by adding bacterial strains isolated from the landfill site. Further genetic manipulation of these organisms produced more than 100 recombinant bacteria, which have been tested for their usefulness in reactors. It was demonstrated that significant cost savings will be possible, if SBR treatment is used before the carbon absorption stage.

Several other companies that are reported to be active in toxic site clean-up in USA include the following: Detox Industries, Kerr-McGee Polybac and Sybrom Chemical. The development in this field have regularly been highlighted in several international symposia held during the last decade.